| 1 |  Manuel Blanco Encalada Chilean politician and President (1790-1876) | Sep 9, 1826 | Jul 9, 1826 |
| 2 |  Ramón Freire Chilean politician (1787-1851) | May 8, 1827 | Feb 15, 1827 |
| 3 |  Francisco Antonio Pinto Chilean politician and President (1785-1858) | Nov 2, 1829 | Oct 19, 1829 |
| 4 |  Francisco Ramón Vicuña President of Chile (1775-1849) | Dec 7, 1829 | Nov 2, 1829 |
| 5 |  José Tomás Ovalle Chilean political figure, president | Mar 8, 1831 | Apr 1, 1830 |
| 6 |  José Joaquín Prieto Chilean politician and President (1786-1854) | Sep 18, 1841 | Sep 18, 1831 |
| 7 |  Manuel Bulnes Chilean politician and President (1799-1866) | Sep 18, 1851 | Sep 18, 1841 |
| 8 |  Manuel Montt Chilean politician (1809–1880) | Sep 18, 1861 | Sep 18, 1851 |
| 9 |  José Joaquín Pérez Chilean politician and President (1801-1889) | Sep 18, 1871 | Sep 18, 1861 |
| 10 |  Federico Errázuriz Zañartu Chilean politician (1825-1877) | Sep 18, 1876 | Sep 18, 1871 |
| 11 |  Aníbal Pinto Chilean politician and President (1825-1884) | Sep 18, 1881 | Sep 18, 1876 |
| 12 |  Domingo Santa María Chilean politician and President (1825–1889) | Sep 18, 1886 | Sep 18, 1881 |
| 13 |  José Manuel Balmaceda Chilean politician and President (1840-1891) | Aug 29, 1891 | Sep 18, 1886 |
| 14 |  Jorge Montt Chilean sailor, politician and president (1845-1922) | Sep 18, 1896 | Dec 26, 1891 |
| 15 |  Federico Errázuriz Echaurren President of Chile (1850-1901) | Jul 12, 1901 | Sep 18, 1896 |
| 16 |  Aníbal Zañartu Chilean politician and Vice President (1847-1902) | Sep 18, 1901 | Jul 12, 1901 |
| 17 |  Germán Riesco Chilean politician and president (1854-1916) | Sep 18, 1906 | Sep 18, 1901 |
| 18 |  Pedro Montt Chilean politician (1849–1910) | Aug 16, 1910 | Sep 18, 1906 |
| 19 |  Elías Fernández Albano Chilean politician (1845-1910) | Sep 6, 1910 | Aug 16, 1910 |
| 20 |  Emiliano Figueroa President of Chile (1866-1931) | Dec 23, 1910 | Sep 6, 1910 |
| 21 |  Ramón Barros Luco Chilean politician and President (1835–1919) | Dec 23, 1915 | Dec 23, 1910 |
| 22 |  Juan Luis Sanfuentes Chilean politician and President (1858-1930) | Dec 23, 1920 | Dec 23, 1915 |
| 23 |  Arturo Alessandri Chilean politician and President (1868–1950) | Sep 12, 1924 | Dec 23, 1920 |
| 24 |  Carlos Ibáñez del Campo Chilean army officer and political figure (1877-1960) | Jul 26, 1931 | Jul 21, 1927 |
| 25 |  Juan Esteban Montero Chilean political figure (1879–1948) | Jun 4, 1932 | Dec 4, 1931 |
| 26 |  Carlos Dávila Chilean diplomat, journalist and politician (1887-1955) | Jul 8, 1932 | Jun 16, 1932 |
| 27 |  Pedro Aguirre Cerda Chilean politician and president (1879-1941) | Nov 25, 1941 | Dec 24, 1938 |
| 28 |  Juan Antonio Rios Chilean politician and President (1888-1946) | Jun 27, 1946 | Apr 2, 1942 |
| 29 |  Gabriel Gonzáles Videla Chilean politician (1898–1980) | Nov 3, 1952 | Nov 3, 1946 |
| 30 |  Jorge Alessandri Chilean politician and President (1896–1986) | Nov 3, 1964 | Nov 3, 1958 |
| 31 |  Eduardo Frei Montalva President of Chile (1911-1982) | Nov 3, 1970 | Nov 3, 1964 |
| 32 |  Salvador Allende 28th president of Chile (1908–1973) | Sep 11, 1973 | Nov 3, 1970 |
| 33 |  Augusto Pinochet dictator of Chile from 1973 to 1990 | Mar 11, 1990 | Mar 11, 1981 |
| 34 |  Patricio Aylwin Chilean politician and former president (1918–2016) | Mar 11, 1994 | Mar 11, 1990 |
| 35 |  Eduardo Frei Ruiz-Tagle President of Chile from 1994 to 2000 | Mar 11, 2000 | Mar 11, 1994 |
| 36 |  Ricardo Lagos Chilean politician, president of Chile from 2000 to 2006 | Mar 11, 2006 | Mar 11, 2000 |
| 37 |  Michelle Bachelet President of Chile from (2006–2010; 2014–2018) | Mar 11, 2010 | Mar 11, 2006 |
| 38 |  Sebastián Piñera Chilean entrepreneur and politician (1949–2024) | Mar 11, 2014 | Mar 11, 2010 |
| 39 |  Gabriel Boric president of Chile from 2022 to 2026 | Mar 11, 2026 | Mar 11, 2022 |
| 40 |  José Antonio Kast president of Chile since 2026 | — | Mar 11, 2026 |
| 41 | | — | — |